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Stop Leak (for ANY fluid) is something you put in a heap to limp it along long enough to trade it in at a dealership. It's not something you put in a car you want to keep. Such chemicals have a tough time telling the difference between a leak and a valve, narrow passage, etc. I'd think it would be highly likely it would clog your heater core, even if it was nominally compatible with G12.
 

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2001 Passat wagon; 2016 Golf Sportwagen
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The CTS flange transplant is not that painful -- the boys and I fixed it on my elder son's AMB 1.8T (2002 A4) in about 3 hours, working rather slowly and checking each other as we went. When (not if) my wife's AUG 1.8T needs it, I'll bet I can do it in well under 2 hours.
 

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This is all good advice man - and the flange really isn't that difficult - just time consuming. You should be able to do it with modest skill in a few hours - just make sure you've got G12 available as you will lose some.
 
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